Researchers at Osaka University have been able to enhance the power factor of a promising thermoelectric material by more than 100% by varying the pressure, paving the way for new materials with improved thermoelectric properties. Thermoelectric materials have the unique ability to generate electricity from temperature differences and therefore could potentially be used to convert otherwise wasted heat (such as heat from hot laptops or servers) into usable electricity.

In addition to improving the thermoelectric properties of a material, the researchers revealed that the material's thermoelectric properties originate from a transition in the topology of the electronic band structure, which is referred to as the Lifshitz transition. This transition differs from the conventional Landau-type phase transition, because it occurs without any symmetry breaking.

Researchers have long had reason to believe that the Lifshitz transition plays a crucial role in many quantum phenomena, such as superconductivity, complex magnetism, and thermoelectric properties, but they lacked direct proof.

In this new study, Osaka University researchers have shown a direct link between the Lifshitz transition and physical properties in a thermoelectric material. "We were able to keep track of the Lifshitz transition by applying pressure and measuring the quantum oscillations as the pressure was increased," corresponding author Hideaki Sakai says.

The researchers studied tin selenide (SnSe), a thermoelectric material that is also a semiconductor with a small amount of conducting carriers. In semiconductors the lower energy valence band is filled with electrons whereas the higher energy conduction band is empty of them; once some impurities and/or chemical defects are introduced, conducting carriers are introduced as electrons and holes in the conduction and valence bands, respectively, and the semiconductor will behave like a conductor.

Apart from having an effect on the material's electrical conduction properties, the band structure also has an effect on quantum phenomena, such as their thermoelectric abilities. The valence bands of tin selenide are not completely flat, but normally have two valleys in them.

"When we increased the pressure on the material, we observed a change from two to four valleys in the material when the Lifshitz transition occurred," Hideaki Sakai says. The researchers were able to show both experimentally and theoretically that this change in the number of valleys was directly responsible for significantly improving tin selenide's thermoelectric properties.

The results of the study may help prepare improved thermoelectric materials in the future and could also help clarify the effect of the Lifshitz transition on various transport properties, leading to potential applications such as novel electronics utilizing valley degrees of freedom in the band structure.

Research Report: "Large Enhancement of Thermoelectric Efficiency Due to a Pressure-Induced Lifshitz Transition in SnSe"

Related Links
Osaka University
Bio Fuel Technology and Application News

Tweet

Thanks for being here; We need your help. The SpaceDaily news network continues to grow but revenues have never been harder to maintain. With the rise of Ad Blockers, and Facebook - our traditional revenue sources via quality network advertising continues to decline. And unlike so many other news sites, we don't have a paywall - with those annoying usernames and passwords. Our news coverage takes time and effort to publish 365 days a year. If you find our news sites informative and useful then please consider becoming a regular supporter or for now make a one off contribution.
SpaceDaily Contributor $5 Billed Once credit card or paypal		SpaceDaily Monthly Supporter $5 Billed Monthly paypal only

Efficiently producing fatty acids and biofuels from glucose
Seoul, South Korea (SPX) Jun 24, 2019
Researchers have presented a new strategy for efficiently producing fatty acids and biofuels that can transform glucose and oleaginous microorganisms into microbial diesel fuel, with one-step direct fermentative production. The newly developed strain, created by Distinguished Professor Sang Yup Lee and his team, showed the highest efficiency in producing fatty acids and biodiesels ever reported. It will be expected to serve as a new platform to sustainably produce a wide array of fatty acid-based ... read more